Tatiana Besset - Publications
2022
| [75] J. Fichez, D Dupommier, T. Besset,* Synthesis. 2022, 10.1055/s-0040-1719891 Direct Synthesis of Disubstituted Trifluoromethylthiolated Alkenes (Review) |  |
| [74] M. Gao, M. Vuagnat, P. Jubault, T. Besset Eur. J. Org. Chem. 2022, e202101255. DOI: 10.1002/ejoc.202101255 Very important paper N-Thiocyanato-2,10-camphorsultam Derivatives: Design and Applications of Original Electrophilic Thiocyanating Reagents Invited contribution for the Eur. J. Org. Chem. Special Issue honoring Prof. Ferenc Fülöp. |  |
2021
| [73] E. Nobile, T. Castanheiro, T. Besset,* Chem. Comm. 2021, 57, 12337. DOI: 10.1039/d1cc04737j C–H Electrophilic (phenylsulfonyl)difluoromethylation of (hetero)arenes with a newly designed reagent |  |
| [72] F. Petit-Cancelier, S. Couve-Bonnaire, T. Besset* Tetrahedron. 2021, 98 132446. DOI: 10.1016/j.tet.2021.132446 Synthesis of a Library of SCF2CO2Et Reagents: An Access To Original (Ethoxycarbonyl)difluoromethylthioesters Invitation for a special Issue in Tetrahedron entitled "Fluorine and Chalcogens" |  |
| [71] L. Ruyet, T. Poisson, T. Besset* Eur. J. Org. Chem. 2021,6145. DOI: 10.1002/ejoc.202100580 Transition Metal-Free Regioselective Remote C-H Bond 2,2,2-Trifluoroethoxylation of 8-Aminoquinoline Derivatives at the C5 Position |  |
| [70] L. Ruyet, M. I. Lapuh, V. S. Koshti, T. Földesi, P. Jubault, T. Poisson, Z. Novák, T. Besset* Chem. Commun. 2021, 57, 6241. DOI: 10.1039/d1cc02007b Z-Selective Pd-catalyzed 2,2,2-trifluoroethylation of acrylamides at room temperature Invitation for a special Theme Collection “Functionalization of unreactive C-H bonds” Highlight dans En direct des laboratoires
|  |
[69] T. Charvillat, P. Bernardelli, M. Daumas, X. Pannecoucke, V. Ferey, T. Besset* Chem. Soc. Rev. 2021, 50, 8178. DOI: 10.1039/d0cs00736f Hydrogenation of fluorinated molecules: an overview (Review) |  |
| [68] M. Gao, M. Vuagnat, M.-Y. Chen, X. Pannecoucke, P. Jubault, T. Besset* Chem. Eur J. 2021, 27, 6145. DOI: 10.1002/chem.202004974 Design and Use of Electrophilic Thiocyanating and Selenocyanating Reagents: a New Trend for the Construction of SCN- and SeCN-containing Compounds”(Review) This article also appears in Reviews Showcase |  |
2020
| [67] X. Huang, E. David, P. Jubault, T. Besset, S. Couve-Bonnaire,* J. Org. Chem. 2020, 85, 14055. DOI: 10.1021/acs.joc.0c02081. Organocatalyzed Sulfa-Michael Addition of Thiophenols on Trisubstituted α-Fluoroacrylates, a Straightforward Access to Chiral Fluorinated Compounds |  |
| [66] S. Mazeh, I. Lapuh,T. Besset* CHIMIA 2020, 74, 871. DOI: 10.2533/chimia.2020.871. Advances in the Synthesis of Fluorinated Scaffolds by Transition Metal-Catalyzed C-H Bond Activation (Review) Invitation for a special issue on ’Innovative Tools in Organic Chemistry | |
| [65] I. Lapuh, S. Mazeh, T. Besset* ACS Catal. 2020, 10, 12898. DOI: 10.1021/acscatal.0c03317. Chiral Transient Directing Groups in Transition-Metal-Catalyzed Enantioselective C–H Bond Functionalization (Review) |  |
| [64] M. Gao, M.-Y. Chen, X. Pannecoucke, P. Jubault, T. Besset* Chem. Eur. J.2020, 26,15497. DOI: 10.1002/chem.202003521. Pd‐Catalyzed Directed Thiocyanation Reaction by C–H Bond Activation Part of a Special Issue celebrating the 1000th Issue of Chemistry—A European Journal. This article also appears in Hot Topic: C-H Activation, XXII International Symposium on Homogeneous Catalysis |  |
| [63] E. Nobile, T. Castanheiro, T. Besset* Angew. Chem. Int. Ed.2021, 60, 12170. DOI: 0.1002/ange.202009995. Radical‐Promoted Distal C‐H Functionalization of C(sp3) Centers with Fluorinated Moieties (Review) |  |
| [62] M.-Y. Chen, X. Pannecoucke, P. Jubault, T. Besset* Org. Lett. 2020, 22, 7556. DOI: 10.1021/acs.orglett.0c02750. Pd-Catalyzed Selective Chlorination of Acrylamides at Room Temperature |  |
| [61] L. Ruyet, T. Besset* Beilstein J. Org. Chem. 2020, 16, 1051. DOI:10.3762/bjoc.16.92. Copper-based fluorinated reagents for the construction of CF2R-containing molecules (R ≠ F). (Review) |  |
| [60] M. Barday, R. Blieck, L. Ruyet, T. Besset Tetrahedron 2020, DOI: 10.1016/j.tet.2020.131153 Remote trifluoromethylthiolation of alcohols under visible light Invited contribution for the special issue for Nuno Maulide |  |
| [59] K. Balanna, K. Madica, S. Mukherjee, A. Ghosh, T. Poisson, T. Besset, G. Jindal, A.T. Biju Chem. Eur J. 2020, 26, 818, DOI: 10.1002/chem.201905177 N-Heterocyclic Carbene-Catalyzed Formal [6+2] Annulation Reaction via Cross-Conjugated Aza-Trienolate Intermediates |  |
| [58] F. Petit-Cancelier, B. François, X. Pannecoucke, S. Couve-Bonnaire, T. Besset Adv. Synth. Catal. 2020, 362,760, DOI: 10.1002/adsc.201901454 S-(Diethyl phosphonodifluoromethyl)Benzenesulfonothioate: A New Reagent for the Synthesis of SCF2PO(OEt)2-containing Molecules |  |
2019
| [57] M.-Y. Chen, X. Pannecoucke, P. Jubault, T. Besset* J. Org. Chem. 2019, DOI: 10.1021/acs.joc.9b01872 Access to Isothiazolones from Simple Acrylamides by Pd-Catalyzed C−H Bond Activation Invited contribution for the special issue on "C-H Bond Functionalization" |  |
| [56] J. Wang, H.-Y. Xiong, E. Petit, L. Bailly, X. Pannecoucke, T. Poisson, T. Besset* Chem. Commun 2019, 55, 8784 BiCl3-Mediated Direct Functionalization of Unsaturated C–C Bonds with an Electrophilic SCF2PO(OEt)2 Reagent |  |
| [55] E. Carbonnel, T. Poisson, P. Jubault, X. Pannecoucke, T. Besset* Front Chem. 2019, 7,111, DOI: 10.3389/fchem.2019 Recent Advances for the Direct Introduction of the CF2Me Moiety | |
| [54] X. Pannecoucke, T. Besset* Org. Biomol. Chem, 2019, 1683 DOI: 10.1039/C8OB02995D Use of ArSO2SRf Reagents: An Efficient Tool for the Introduction of SRf Moieties (Review – Invited contribution for Organic & Biomolecular Chemistry New Talent themed issue) |  |
2018
| [52] A Bouchard, V. Kairouz, M. Manneveau, H.-Y. Xiong, T. Besset*, X. Pannecoucke, H. Lebel* J. Flow Chem. 2018, DOI: 10.1007/s41981-018-0023-4 Continuous flow palladium-catalyzed trifluoromethylthiolation of C-H bonds | |
| [51] S. Mukherjee, S. Shee, T. Poisson, T. Besset, A. T. Biju*, Org. Lett. 2018, 30, 6998, Enantioselective N-Heterocyclic Carbene-Catalyzed Cascade Reaction for the Synthesis of Pyrroloquinolines via N-H Functionalization of Indoles. |  |
| [50] Q. Zhao, M.-Y. Chen, T. Poisson, X. Pannecoucke, J.-P. Bouillon, T. Besset, Eur. J. Org. Chem. 2018, DOI: 10.1002/ejoc.201801071. Pd‐Catalyzed Trifluoromethylthiolation of Unsaturated Compounds: A General Approach |  |
| [49] Q. Zhao, J. Wang, T. Besset, X. Pannecoucke, J.-P. Bouillon, T. Poisson, Tetrahedron 2018, 74, 6033. Palladium-catalyzed synthesis of 3-trifluoromethylated 1,3-dienes from acrylate derivatives and BTP |  |
| [48] C. Sambiagio, D. Schönbauer, R. Blieck, T. Dao-Huy, G. Pototschnig, P. Schaaf, T. Wiesinger, M. F. Zia, J. Wencel-Delord, T. Besset, B. U. W. Maes, M. Schnürch, Chem. Soc. Rev. 2018, 47, 6603. A comprehensive overview of directing groups applied in metal catalysed C–H functionalisation chemistry |  |
| [47] F. Gelat, A. Patra, X. Pannecoucke, A.T. Biju, T. Poisson*, T. Besset*, Org. Lett. 2018, 20, 3897. N-Heterocyclic Carbene-Catalyzed Synthesis of α-Trifluoromethyl Esters Highlighted in Chemistry Views |  |
| [46] F. Gelat, T. Poisson, X. Pannecoucke, A. T. Biju, T. Besset*, Eur. J. Org. Chem. 2018, DOI : 10.1002/ejoc.201800418. Trifluoromethylthiolation of α-Chloroaldehydes: Access to Quaternary SCF3-Containing Centers Selected as Very Important Paper |  |
| [45] E. Carbonnel, X. Pannecoucke, T. Besset, P. Jubault, T. Poisson Chem Commun. 2018, 54, 2491 |  |
| [44] MA. Patra, F. Gelat, X. Pannecoucke, T. Poisson, T. Besset, A.T. Biju Org. Lett. 2018, 20, 1086 |  |
| [43] M. V. Ivanova, T. Besset, X. Pannecoucke, T. Poisson Synthesis. 2018, 50, 778 |  |
2017
| [42] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke, T. Poisson Chem.Eur. J. 2017, 23,17318 |  |
| [41] Q. Zhao, T. Poisson, X. Pannecoucke, T. Besset Synthesis. 2017,49, 4808 |  |
| [40] Q. Zhao, T. Poisson, X. Pannecoucke, J.P. Bouillon, T. Besset Org.Lett. 2017, 19, 5106 |  |
| [39] E. Carbonnel, T. Besset, T. Poisson, D. Labar, X. Pannecoucke, P. Jubault Chem Commun. 2017, 53, 5706 18F-Fluoroform: a 18F-trifluoromethylating agent for the synthesis of SCF218F-aromatic derivatives |  |
| [38] Q. Zhao, V. Tognetti, L. Joubert, T. Besset, X. Pannecoucke, J.-P. Bouillon, T. Poisson Org. Lett. 2017, 19, 2106 Palladium-Catalyzed Synthesis of 3-Trifluoromethyl Substituted 1,3-Butadienes by Means of Directed C-H Bond Functionalization |  |
| [37] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke, T. Poisson Eur. J. Org. Chem. 2017, 2475 Copper Mediated (Diethyl phosphono)difluoromethylthiolation of α-Bromo-Ketones |  |
| [36] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke, T. Poisson Angew.Chem. Int. Ed. 2016, 55, 14141 Copper Salt-Controlled Divergent Reactivity of [Cu]CF2PO(OEt)2 with α-Diazocarbonyl Derivatives |  |
| [35] H.-Y. Xiong, X. Pannecoucke, T. Besset* Angew. Chem. Int. Ed. 2016, 55, 13490 Press release by CNRS A New Electrophilic Reagent for the Direct Introduction of the SCF2PO(OEt)2 Group onto Molecules |  |
| [34] H.-Y. Xiong, X. Pannecoucke, T. Besset,* Chem. Eur. J. 2016, 22, 16734 Recent Advances in the Synthesis of SCF2H- and SCF2FG-containing Molecules |  |
| [33] H.-Y. Xiong, D. Cahard, X. Pannecoucke, T. Besset* Eur. J. Org. Chem. 2016, 3625 Pd-Catalyzed Directed Chlorination of Unactivated C(sp3)-H Bonds at Room Temperature |  |
| [32] T. Besset, P. Jubault, X. Pannecoucke, T. Poisson* Org. Chem. Front. 2016, 3, 1004 New Entries Toward the Synthesis of OCF3-Containing Molecules |  |
| [31] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke, T. Poisson* Chem. Eur. J. 2016, 22, 10284 New Prospects Toward the Synthesis of Difluomethylated Phosphate Mimics |  |
| [30] H.-Y. Xiong, X. Pannecoucke, T. Besset* Org. Chem. Front. 2016, 3, 620 Oxidative Trifluoromethylthiolation and Thiocyanation of Amines: a General Approach to N–S Bond Formation |  |
| [29] Q. Zhao, T. Besset, T. Poisson, J.-P. Bouillon,* X. Pannecoucke Eur. J. Org. Chem. 2016, 76 Palladium-Catalysed Synthesis of α-(Trifluoromethyl)styrenes by Means of Directed C–H Bond Functionalization |  |
2015
J. N. H. Reek, W. Riethorst, F. Zepeck, W. Kroutil*
Adv. Synth. Cat. 2014, 356, 2257
Dynamic Kinetic Resolution of 2-Phenylpropanal Derivatives to Yield β-Chiral Primary Amines via Bioamination
J. N. H. Reek, W. Riethorst, F. Zepeck, W. Kroutil*
Adv. Synth. Cat. 2014, 356, 2257
Dynamic Kinetic Resolution of 2-Phenylpropanal Derivatives to Yield β-Chiral Primary Amines via Bioamination
| [17] T. Ferrary, E. David, G. Milanole, T. Besset, P. Jubault,* X. Pannecouke Org. Lett. 2013, 15, 5598 A straightforward and highly diastereoselective access to functionalized monofluorinated cyclopropanes via a Michael Initiated Ring Closure reaction |  |
| [16] T. Besset,* R. Gramage-Doria, J. N. H. Reek* Angew. Chem. Int. Ed. 2013, 52, 8795 Remotely Controlled Iridium-Catalyzed Asymmetric Hydrogenation of Terminal 1,1-Diaryl Alkenes |  |
Angew. Chem. Int. Ed. 2013, 52, 8795
Remotely Controlled Iridium-Catalyzed Asymmetric Hydrogenation of Terminal 1,1-Diaryl Alkenes
[15] T. Besset, R. Gramage-Doria, J. N. H. Reek*
Curr. Org. Chem. 2013, 17, 1489
Transition-Metal Encapsulation within Supramolecular Diphosphine Capsules.” Special issue on "Nanoreactors and molecular prisons
[14] D. Anselmo, R. Gramage-Doria, T. Besset, M. V. Escárcega-Bobadilla, G. Salassa, E. C. Escudero-Adán,
M. Martínez Belmonte, E. Martin,J. N. H. Reek,* A. W. Kleij*
Dalton Trans. 2013, 42, 7595
Supramolecular Bulky Phosphines Comprising of 1,3,5-Triaza-7-phosphaadamantane and Zn(salphen)s: Structural Features and Application in Hydrosilylation Catalysis
[13] T. Besset, D. W. Norman, J. N. H. Reek
Adv. Synth. Catal. 2013, 355, 348
Supramolecular Encapsulated Rhodium Catalysts for Branched Selective Hydroformylation of Alkenes at High Temperature
[12] F. W. Patureau, T. Besset, F. Glorius,* checked by T. Harada, T. Fukuyama
Org. Synth. 2013, 90, 41
Preparation of (E)-N,N-Diethyl-2-styrylbenzamide by Rh-catalyzed C-H activation
2012
[11] T. Besset, C. Schneider, D. Cahard*
Angew. Chem. Int. Ed. 2012, 51, 5048
Tamed (Hetero)Arene Trifluoromethylation
[10] F. W. Patureau, T. Besset, R. Fröhlich, F. Glorius*
C. R. Chim. 2012, 15, 1081
On the selectivity in some Rh(III) catalyzed C-H activation cross-couplings; De la sélectivité dans des réactions d'hétéro-couplage par C-H activation catalysées au Rh(III)
[9] N. Schroder, T. Besset, F. Glorius*
Adv. Synth. Catal. 2012, 354, 579
Synthesis of Olefin-Oxazoline-Ligands (OlefOx) by Rhodium(III)-Catalyzed Oxidative Olefination
2011
[8] T. Besset, N. Kuhl, F. W. Patureau, F. Glorius*
Chem. Eur. J. 2011, 17, 7167
Rh(III)-Catalyzed Oxidative Olefination of Vinylic C-H Bonds: Efficient and Selective Access to Di-unsaturated -Amino Acid Derivatives and other Linear 1,3-Butadienes
[7] T. Besset, E. Braud,* C. Garbay, S. Kolb, P.-M. Léo, C. Morin*
Eurjchem 2011, 2, 433
Preparation and evaluation of a set of bis-(methoxycarbonyl-methylthio)-heteroquinones as CDC25B phosphatase inhibitors
[6] S. Rakshit, C. Grohmann, T. Besset, F. Glorius*
J. Am. Chem. Soc. 2011, 133, 2350
Rh[III]-catalyzed directed C-H olefination using an internal oxidant: mild, efficient and versatile
[5] F. W. Patureau, T. Besset, N. Kuhl, F. Glorius*
J. Am. Chem. Soc. 2011, 133, 2154
Diverse strategies towards indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes
[4] F. W. Patureau, T. Besset, F. Glorius*
Angew. Chem. Int. Ed. 2011, 50, 1064
Rhodium-Catalyzed Oxidative Olefination of C-H Bonds in Acetophenones and Benzamides
2009
[3] T. Besset, C. Morin*
Synthesis 2009, 1753
Synthesis of 3,6-Dimethoxybenzene-1,2-diamine and of 4,7-Dimethoxy-2-methyl-1H-benzimidazole
2008
[2] C. Morin, T. Besset, J.-C. Moutet, M. Fayolle, M. Brueckner, D. Limosin, K. Becker, E. Davioud-Charvet*
Org. Biomol. Chem. 2008, 6, 2731
The aza-analogues of 1,4-naphthoquinones are potent substrates and inhibitors of plasmodial thioredoxin and glutathione reductases and of human erythrocyte glutathione reductase
2007
[1] I. Abrunhosa-Thomas, O. Roy, M. Barra, T. Besset, P. Chalard,* Y. Troin*
Synlett 2007, 1613
Diastereoselective synthesis of 2-monosubstituted and 2,6-disubstituted piperidines
Patents
[1] T. R. M.-L. Besset, D. W. Norman, J. N. H. ReekPCT Int. Appl. (2013),
WO 2013181190 A1 20131205. “Catalysts and processes for preparing aldehydes.”
[2] D. W. Norman, J. N. H. Reek, T. R. M.-L. Besset
PCT Int. Appl. (2013),
WO 2013181186 A1 20131205. “Hydroformylation catalysts and process for producing aldehydes.”
