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Tatiana Besset - Publications



Publications


201720162015 - 2014 - 2013 - 2012 - 2011 - 2009 - 2008 - 2007

2017
[39] E. Carbonnel, T. Besset,  T. Poisson,  D. Labar, X. Pannecoucke,  P. Jubault
Chem Commun. 2017, 53, 5706
18F-Fluoroform: a 18F-trifluoromethylating agent for the synthesis of SCF218F-aromatic derivatives

[38] Q. Zhao, V. Tognetti, L. Joubert, T. Besset, X. Pannecoucke, J.-P. Bouillon, T. Poisson
Org. Lett. 2017, 19, 2106
Palladium-Catalyzed Synthesis of 3-Trifluoromethyl Substituted 1,3-Butadienes by Means of Directed C-H Bond Functionalization


[37] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke,
T. Poisson
Eur. J. Org. Chem. 2017, 2475
Copper Mediated (Diethyl phosphono)difluoromethylthiolation of α-Bromo-Ketones


2016
[36] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke,
T. Poisson
Angew.Chem. Int. Ed. 2016, 55, 14141
Copper Salt-Controlled Divergent Reactivity of [Cu]CF2PO(OEt)2 with α-Diazocarbonyl Derivatives
 

[35] H.-Y. Xiong, X. Pannecoucke, T. Besset*
Angew. Chem. Int. Ed. 2016, 55, 13490
Press release by CNRS

A New Electrophilic Reagent for the Direct Introduction of the SCF2PO(OEt)2 Group onto Molecules
 


[34] H.-Y. Xiong, X. Pannecoucke, T. Besset,*
Chem. Eur. J. 2016, 22, 16734
Recent Advances in the Synthesis of SCF2H- and SCF2FG-containing Molecules
 


[33] H.-Y. Xiong, D. Cahard, X. Pannecoucke, T. Besset*
Eur. J. Org. Chem. 2016, 3625
Pd-Catalyzed Directed Chlorination of Unactivated C(sp3)-H Bonds at Room Temperature




[32] T. Besset, P. Jubault, X. Pannecoucke, T. Poisson*
Org. Chem. Front. 2016, 3, 1004
New Entries Toward the Synthesis of OCF3-Containing Molecules




[31] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke,
T. Poisson*

Chem. Eur. J. 2016, 22, 10284
New Prospects Toward the Synthesis of Difluomethylated Phosphate Mimics



[30] H.-Y. Xiong, X. Pannecoucke, T. Besset*
Org. Chem. Front. 2016, 3, 620
Oxidative Trifluoromethylthiolation and Thiocyanation of Amines: a General Approach to N–S Bond Formation
 


[29] Q. Zhao, T. Besset, T. Poisson, J.-P. Bouillon,*
X. Pannecoucke

Eur. J. Org. Chem. 2016, 76
Palladium-Catalysed Synthesis of α-(Trifluoromethyl)styrenes by Means of Directed C–H Bond Functionalization


2015 
[28] M. I. Ivanova, A. Bayle, T. Besset, T. Poisson,*
X. Pannecoucke

Angew. Chem. Int. Ed. 2015, 54, 13406
Copper-Mediated Formation of Aryl, Heteroaryl, Vinyl and Alkynyl Difluoromethylphosphonates: A Mild and General Approach to Fluorinated Phosphate Mimics



[27] T. Besset,* T. Poisson,* X. Pannecoucke
J. Fluorine Chem. 2015, 178, 225
1,4-Addition of the CF3 group, perfluoroalkyl groups and functionalized difluoromethylated moieties: An overview




[26] M.-C. Belhomme, T. Besset, T. Poisson,* X. Pannecoucke
Chem. Eur. J. 2015, 21, 12836
Recent Progress Toward the Introduction of Functionalized Difluoromethylated building blocks




[25] H.-Y. Xiong, T. Besset,* D. Cahard, X. Pannecoucke
J. Org. Chem. 2015, 80, 4204
Palladium(II)-Catalyzed Directed Trifluoromethylthiolation of Unactivated C(sp3)-H Bonds




[24] T. Besset,* T. Poisson,* X. Pannecoucke
Eur. J. Org. Chem. 2015, 2765
Direct Vicinal Difunctionalization of Alkynes: An Efficient Approach Towards the Synthesis of Highly Functionalized Fluorinated Alkenes


2014
[23] T. Besset,* T. Poisson,* X. Pannecoucke
Chem. Eur. J. 2014, 20, 16830
Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of C H Bond Functionalization




[22] T. Besset,* T. Poisson,* X. Pannecoucke
Eur. J. Org. Chem. 2014, 7220
Access to Difluoromethylated Alkynes through the Castro-Stephens Reaction



[21] T. Besset,* D. Cahard,* X. Pannecoucke
J. Org. Chem. 2014, 79, 413
Regio- and Diastereoselective Direct Cu-Mediated Trifluoromethylation of Functionalized Alkenes


[20] M.-C. Belhomme, D. Dru, H.-Y. Xiong, D. Cahard, T. Besset,* T. Poisson,* X. Pannecoucke
Synthesis 2014, 1859
Copper Mediated Direct Functionalization of Unsaturated C–C Bonds using BrCF2CO2Et: a Straightforward Access to Highly Valuable Difluoroacetylated Alkenes.” (Special Topic Issue on “Copper Chemistry” ed. Prof. E. M. Carreira)


[19] V. Bizet, T. Besset, J. A. Ma, D. Cahard*
Curr. Top. Med. Chem. 2014, 14, 901
Recent Progress in Asymmetric Fluorination and Trifluoromethylation Reactions



[18] C. S. Fuchs, M. Hollauf, M. Meissner, R. C. Simon, T. Besset
J. N. H. Reek, W. Riethorst, F. Zepeck, W. Kroutil*

Adv. Synth. Cat. 2014, 356, 2257
Dynamic Kinetic Resolution of 2-Phenylpropanal Derivatives to Yield β-Chiral Primary Amines via Bioamination
 



2013
[17] T. Ferrary, E. David, G. Milanole, T. Besset, P. Jubault,*
X. Pannecouke

Org. Lett. 2013, 15, 5598
A straightforward and highly diastereoselective access to functionalized monofluorinated cyclopropanes via a Michael Initiated Ring Closure reaction



[16] T. Besset,* R. Gramage-Doria, J. N. H. Reek*
Angew. Chem. Int. Ed. 2013, 52, 8795
Remotely Controlled Iridium-Catalyzed Asymmetric Hydrogenation of Terminal 1,1-Diaryl Alkenes












































































[15] T. Besset, R. Gramage-Doria, J. N. H. Reek*
Curr. Org. Chem. 2013, 17, 1489
Transition-Metal Encapsulation within Supramolecular Diphosphine Capsules.” Special issue on "Nanoreactors and molecular prisons

[14] D. Anselmo, R. Gramage-Doria, T. Besset, M. V. Escárcega-Bobadilla, G. Salassa, E. C. Escudero-Adán,
M. Martínez Belmonte, E. Marti
n,J. N. H. Reek,* A. W. Kleij*
Dalton Trans. 2013, 42, 7595
Supramolecular Bulky Phosphines Comprising of 1,3,5-Triaza-7-phosphaadamantane and Zn(salphen)s: Structural Features and Application in Hydrosilylation Catalysis

[13] T. Besset, D. W. Norman, J. N. H. Reek
Adv. Synth. Catal. 2013, 355, 348
Supramolecular Encapsulated Rhodium Catalysts for Branched Selective Hydroformylation of Alkenes at High Temperature

[12] F. W. Patureau, T. Besset, F. Glorius,* checked by T. Harada, T. Fukuyama
Org. Synth. 2013, 90, 41
Preparation of (E)-N,N-Diethyl-2-styrylbenzamide by Rh-catalyzed C-H activation  



2012
[11] T. Besset, C. Schneider, D. Cahard*
Angew. Chem. Int. Ed. 2012, 51, 5048
Tamed (Hetero)Arene Trifluoromethylation

[10] F. W. Patureau, T. Besset, R. Fröhlich, F. Glorius*
C. R. Chim. 2012, 15, 1081
On the selectivity in some Rh(III) catalyzed C-H activation cross-couplings; De la sélectivité dans des réactions d'hétéro-couplage par C-H activation catalysées au Rh(III)

[9] N. Schroder, T. Besset, F. Glorius*
Adv. Synth. Catal. 2012, 354, 579
Synthesis of Olefin-Oxazoline-Ligands (OlefOx) by Rhodium(III)-Catalyzed Oxidative Olefination 


2011
[8] T. Besset, N. Kuhl, F. W. Patureau, F. Glorius*
Chem. Eur. J. 2011, 17, 7167
Rh(III)-Catalyzed Oxidative Olefination of Vinylic C-H Bonds: Efficient and Selective Access to Di-unsaturated -Amino Acid Derivatives and other Linear 1,3-Butadienes

[7] T. Besset, E. Braud,* C. Garbay, S. Kolb, P.-M. Léo, C. Morin*
Eurjchem 2011, 2, 433
Preparation and evaluation of a set of bis-(methoxycarbonyl-methylthio)-heteroquinones as CDC25B phosphatase inhibitors

[6] S. Rakshit, C. Grohmann, T. Besset, F. Glorius*
J. Am. Chem. Soc. 2011, 133, 2350
Rh[III]-catalyzed directed C-H olefination using an internal oxidant: mild, efficient and versatile

[5] F. W. Patureau, T. Besset, N. Kuhl, F. Glorius*
J. Am. Chem. Soc. 2011, 133, 2154
Diverse strategies towards indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes

[4] F. W. Patureau, T. Besset, F. Glorius*
Angew. Chem. Int. Ed. 2011, 50, 1064
Rhodium-Catalyzed Oxidative Olefination of C-H Bonds in Acetophenones and Benzamides 


2009
[3] T. Besset, C. Morin*
Synthesis 2009, 1753
Synthesis of 3,6-Dimethoxybenzene-1,2-diamine and of 4,7-Dimethoxy-2-methyl-1H-benzimidazole

2008
[2] C. Morin, T. Besset, J.-C. Moutet, M. Fayolle, M. Brueckner, D. Limosin, K. Becker, E. Davioud-Charvet*
Org. Biomol. Chem. 2008, 6, 2731
The aza-analogues of 1,4-naphthoquinones are potent substrates and inhibitors of plasmodial thioredoxin and glutathione reductases and of human erythrocyte glutathione reductase 

2007
[1] I. Abrunhosa-Thomas, O. Roy, M. Barra, T. Besset, P. Chalard,* Y. Troin*
Synlett 2007, 1613
Diastereoselective synthesis of 2-monosubstituted and 2,6-disubstituted piperidines 

Patents


[1] T. R. M.-L. Besset, D. W. Norman, J. N. H. Reek
PCT Int. Appl. (2013),
WO 2013181190 A1 20131205. “Catalysts and processes for preparing aldehydes.”

[2] D. W. Norman, J. N. H. Reek, T. R. M.-L. Besset
PCT Int. Appl. (2013),
WO 2013181186 A1 20131205. “Hydroformylation catalysts and process for producing aldehydes.”